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ZINC • METALLIC MINERAL

Zinc Ore & Sphalerite Context in Pakistan

Zinc resources in Pakistan are primarily associated with Mississippi Valley-type (MVT) sediment-hosted sulfide deposits and hydrothermal vein systems. Sourcing evaluations must distinguish between raw zinc-bearing ore, hand-cobbed lump, and beneficiated flotation concentrates.

Product Form
Flotation Concentrate / Sulfide Lump
Main Assay
Target Zn % (Lot-Specific Verification)
Regional Context
Lasbela-Khuzdar MVT Belt, Balochistan
Evidence Category
Official Production Evidence (P)
Representative zinc ore specimen featuring lustrous dark sphalerite crystals on matrix
Representative mineral material: Resinous sphalerite with minor chalcopyrite on host carbonate rock. Occurrence does not constitute available inventory.
Representative material specimen. Occurrence does not constitute available inventory. Consignment verification required.

Mandatory Claim Boundary & Sourcing Notice: This page describes mineral/material evidence and buyer requirements. It does not represent current Enigma Earth inventory. Source, ownership, grade, quantity and availability must be verified for the specific enquiry.

GEOLOGICAL APPRAISAL

Mineralogy & Geological Occurrence

Zinc mineralization in Pakistan occurs predominantly in stratabound carbonate-hosted sulfide bodies in southern Balochistan and hydrothermal veins in Khyber Pakhtunkhwa. Primary zinc occurs as sphalerite, often intergrown with galena, pyrite, and carbonate gangue.

Geological Setting & Host Formations

The major zinc province is the Lasbela-Khuzdar metallogenic belt of Balochistan, developed in Jurassic Shirinab Formation platform limestones. Subordinate occurrences include hydrothermal sulfide veins in metamorphic rocks of the Kohistan and Besham regions.

Key Mineralogy & Chemical Formula

Primary hypogene zinc is dominated by sphalerite ((Zn,Fe)S), which varies from amber-yellow low-iron varieties to black iron-rich marmatite. Near-surface oxidized zones may contain secondary zinc carbonates (smithsonite) and hydrous silicates (hemimorphite).

Formula: Sphalerite ((Zn,Fe)S), Smithsonite (ZnCO3), Hemimorphite (Zn4Si2O7(OH)2·H2O)
PAKISTAN EVIDENCE

Pakistan Evidence & Regional Context

Zinc extraction in Pakistan is verified through positive official reporting and historical corporate operations at the Duddar underground mine. Occurrence across exploration targets does not establish active commercial production or unencumbered mineral availability.

[P]Official Production Evidence
BalochistanRegional Context

Lasbela-Khuzdar MVT Belt (Duddar, Gunga, Surmai)

Major sediment-hosted MVT lead-zinc deposits. Duddar represents a developed underground extraction project operating under specific concession agreements. Surrounding prospects require formal title and assay verification.

Documented Regional Occurrence
Khyber PakhtunkhwaRegional Context

Besham, Kohistan & Chitral Vein Belts

Hydrothermal polymetallic sulfide veins crosscutting metamorphic basement rocks; exploration context requiring systematic diamond coring.

Documented Regional Occurrence
Evidence Boundary: Geological reports of zinc mineralization in Balochistan and KP do not establish current production capacity, concentrate availability, or commercial off-take rights.
PRODUCT ARCHITECTURE

Commercial Forms & Processing Stages

Commercial requirements must strictly differentiate between raw extraction, sorted grades, and processed products.

01

Zinc Flotation Concentrate

High-grade beneficiated powder produced by selective froth flotation of pulverized sphalerite ore. Standard feed for electrolytic zinc refineries (RLE plants) and thermal smelters.

Fine dewatered powder (80% passing 75 microns / 200 mesh)
02

Zinc-Bearing Direct Shipping Ore (DSO)

Crude run-of-mine ore extracted from high-grade veins. Requires crushing, sizing, and sorting before metallurgical application.

Crushed lump (10 mm to 60 mm)
03

Zinc Oxide / Calamine Ore

Secondary non-sulfide oxidized zinc ore (smithsonite/hemimorphite) suitable for Waelz kiln volatilization or acid leaching.

Screened rock fragments (10 mm to 50 mm)
TECHNICAL QUALIFICATION

Buyer Specification Requirements

Prospective buyers and project owners should specify the parameters below. Values represent typical industrial targets and do not imply universal Pakistani deposit compliance.

Assay & Elemental Composition

6 Parameters
Target Zinc Grade (Zn)
Flotation concentrate typically 48.0% - 54.0% Zn; DSO lump requires lot assay
No universal concentrate spec; lot verification mandatory
Lead Content (Pb)
Typically 1.0% - 3.5% in clean zinc concentrate
Smelter penalty applied if exceeding threshold
Total Iron (Fe)
Typically 4.0% - 9.0% Fe in sphalerite
Higher iron (marmatite) reduces zinc recovery and increases slag
Total Sulfur (S)
Typically 28.0% - 33.0% S in sulfide concentrates
Roasting acid plant balance parameter
Cadmium (Cd)
Typically < 0.25% - 0.30% Cd in clean concentrate
Toxic volatile byproduct; penalty threshold applies > 0.15%
Arsenic (As)
Maximum 0.10% - 0.20% As
Strict environmental and hydrometallurgical leaching penalty

Physical & Moisture Parameters

2 Parameters
Moisture Content
Maximum 8.5% free moisture
TML certification mandatory under IMO IMSBC Code
Product Form & Sizing
Flotation concentrate powder (80% passing 75 microns) vs screened lump (10 mm - 60 mm)
Screen analysis per parcel

Commercial & Lot Parameters

4 Parameters
Consignment Volume (Quantity)
Parcels from 100 MT trial to 2,000 MT commercial lots
Subject to verified supply and mine aggregation
Delivery Destination & Terms
FOB Karachi Port / Port Qasim or CIF nominated destination port
Incoterms 2020 agreed per specific contract
Packaging Standards
1.5 MT heavy-duty UV-stabilized big bags with inner moisture barrier
Tamper-evident seals
Inspection Authority
Independent accredited surveyor (ALS, SGS, Alfred H Knight)
Sampling at load port or designated consolidation depot
VERIFICATION PROTOCOL

Testing & Verification Requirements

Testing and quality verification must be conducted by an appropriate independent laboratory. Commercial transactions require representative sampling, assay, chemical analysis or gemological appraisal, and third-party inspection. Enigma Earth does not maintain a private testing monopoly.

Representative Sampling

Systematic mechanical stream sampling or spear sampling according to ISO 12743 for zinc concentrates. Sealed composite preparation with duplicate umpire reserves.

Standard Test Methods
  • ISO 13658 (Determination of zinc content — Titration / ICP-OES methods)
  • ASTM E945 (Test Method for Determination of Zinc in Ores by EDTA Titrimetric Method)
  • IMO IMSBC Code (Transportable Moisture Limit & Flow Moisture Point testing)
Laboratory Independence

Commercial transactions require third-party accredited laboratory verification. Enigma Earth does not maintain a private assay monopoly; testing must be performed by mutually agreed accredited bodies (e.g. ALS, SGS, Alfred H Knight).

QUALITY CRITERIA

Impurity Tolerances & Critical Penalty Factors

Commercial specifications require explicit thresholds for penalty elements, structural soundness, color uniformity, and treatment parameters.

Iron (Fe) in Sphalerite Lattice

Quality Parameter

Operational Impact: Iron substituting for zinc in marmatite reduces the maximum theoretical zinc grade and increases smelter slag generation

Tolerance: Penalties apply above 8.0% Fe; high iron lowers payable zinc units

Cadmium (Cd)

Quality Parameter

Operational Impact: Toxic volatile byproduct; smelters apply strict environmental handling penalties

Tolerance: Typically tolerated up to 0.30% Cd; penalties apply above 0.15%

Silica (SiO2)

Quality Parameter

Operational Impact: Forms gelatinous silica during acid leaching in RLE plants, blinding filtration equipment

Tolerance: Strict penalty applied > 2.5% SiO2; rejection typically > 4.0%

Arsenic (As) & Mercury (Hg)

Quality Parameter

Operational Impact: Environmental poisons requiring specialized off-gas cleaning and waste disposal

Tolerance: As < 0.20%, Hg < 50 ppm
SUPPLY CHAIN INTEGRITY

Sourcing, Provenance & Preparation Logistics

Due diligence guidelines for legal chain of custody, packaging standards, and maritime export protocols.

Origin Verification & Licensing

All zinc commercial consignments must be accompanied by official provincial transport permits from the Directorate General of Mines & Minerals (DGMM), validated lease numbers, and certified chain-of-custody documentation.

Corporate underground mining operations in the Lasbela-Khuzdar belt are held under sovereign concession agreements. Sourcing from medium-scale operators requires rigorous cadastral and title verification.

Provenance Caution: A geological assay showing elevated zinc in an outcrop or grab sample does not demonstrate that a bulk parcel or deposit is economically viable. Occurrence does not equal extraction or commercial grade.
Packaging & Maritime Transport
  • 1.5 MT heavy-duty UV-stabilized woven polypropylene bulk jumbo bags with inner polyethylene moisture liner
  • Bulk containerized loading with heavy-duty 20ft container liners

Transport via dedicated flatbed trailers to Port Qasim or Karachi Port for containerized or breakbulk maritime freight under IMO IMSBC compliance.

Handling Caution: Zinc concentrate must never be loaded onto vessels if the moisture content exceeds the Transportable Moisture Limit (TML), as liquefaction during ocean transit presents a catastrophic vessel stability hazard.
INQUIRY SUBMISSION GUIDE

What to Send: Technical Requirement Checklist

To evaluate feasibility and structure compliant off-take, please include the following technical details in your enquiry.

1Desired product form (Flotation concentrate vs DSO lump vs oxide ore)
2Target zinc grade range (Zn %) and minimum acceptable threshold
3Comprehensive impurity limit specification (Fe, Pb, Cd, SiO2, As, Hg)
4Consignment volume (trial tonnage vs recurring monthly schedule)
5Preferred packaging (1.5 MT big bags vs bulk containerized)
6Delivery terms (FOB Karachi Port / Port Qasim vs CIF destination port)
7Designated inspection agency (ALS, SGS, Alfred H Knight)
Incomplete RFQs lacking grade cutoffs or consignment volumes cannot be processed.
Submit a Zinc Requirement
FREQUENTLY ASKED QUESTIONS

Frequently Asked Questions: Zinc Ore & Concentrates

Key questions regarding Pakistani mineral availability, testing protocols, and trade qualification.

In modern roast-leach-electrowin (RLE) zinc refineries, soluble silica dissolves in sulfuric acid to form silicic acid gel, which blinds leach-residue filters and severely disrupts plant throughput. Concentrates with silica exceeding 2.5% to 3.5% incur heavy penalties or rejection.

Structured Mineral Qualification

Structure a Compliant Zinc Ore & Concentrates Requirement

Submit technical specifications, target grades, and consignment parameters for structured verification.